3</sub>N<sub>4</sub>) 是一種晶體結(jié)構(gòu)與石墨相似的碳基共軛聚合物材料,在光催化抗菌領(lǐng)域展現(xiàn)出獨(dú)有的潛力。然而, g-C<sub>3</sub>N<sub>4</sub> 光催化劑存在光生電子 (e<sup>-</sup> )和光生空穴 <img src="/qkimages/kjxj/kjxj202503/kjxj20250305-1-l.jpg" with="29px" style="vertical-align: middle;"> )易復(fù)合、太陽(yáng)光吸收不全、比表面積小、吸附性差等問(wèn)題,導(dǎo)致光催化效率低,影響了抗菌效果。采用形貌調(diào)控、貴金屬沉積、元素?fù)诫s、異質(zhì)結(jié)構(gòu)建等手段對(duì) g-C<sub>3</sub>N<sub>4</sub> 進(jìn)行功能化改性,可激發(fā) g-C<sub>3</sub>N<sub>4</sub> 的抗菌潛力。對(duì) g-C<sub>3</sub>N<sub>4</sub> 光催化抗菌性能的優(yōu)化策略進(jìn)行了詳細(xì)介紹,重點(diǎn)綜述了 g-C<sub>3</sub>N<sub>4</sub> 光催化抗菌特性在水消毒、抗菌敷料、抗菌紡織物、食品包裝方面的應(yīng)用研究現(xiàn)狀,指出目前 g-C<sub>3</sub>N<sub>4</sub> 光催化抗菌劑開(kāi)發(fā)面臨的問(wèn)題。為應(yīng)對(duì)日益嚴(yán)峻的微生物污染挑戰(zhàn),其未來(lái)研究可從以下幾個(gè)方面展開(kāi):1)深化活性氧(ROS)對(duì)細(xì)菌細(xì)胞膜破壞,細(xì)胞內(nèi)蛋白質(zhì)、DNA損傷等具體機(jī)制的研究;2)探索 g-C<sub>3</sub>N<sub>4</sub> 對(duì)耐藥菌、常用真菌等廣譜菌的抗菌應(yīng)用研究;3)提升 g-C<sub>3</sub>N<sub>4</sub> 在不同環(huán)境下的適應(yīng)性。-龍?jiān)雌诳W(wǎng)" />

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石墨相氮化碳光催化抗菌優(yōu)化策略及應(yīng)用研究進(jìn)展

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中圖分類號(hào):0643.36;0644.1 文獻(xiàn)標(biāo)識(shí)碼:A DOI:10.7535/hbkd.2025yx03005

Research progress on optimization strategies and applications of photocatalytic antibacterial activity of graphitic carbon nitride

I Wenhui1,WANG Ruopeng1,HAN Yuhe1,WANG Sai1, ZHANG Yumei12,LU Qiong 1,2 ,AN Jing 1,2

(1.School of Sciences,Hebei Universityof Science and Technology,Shijiazhuang,Hebei O50o18,China; .Hebei Provincial KeyLaboratoryof Photoelectric Controlon Surfaceand Interface,Shijiazhuang,Hebei O5oo18,China)

Abstract: Graphitic carbon nitride (g-C3N4 ) is a carbon-based conjugated polymer material with a crystal structure similar to graphite,which exhibitsunique potential inthe fieldof photocatalyticantibacterial activity.However,factorssuch as easy recombination of photogenerated electron Ξ(e-) -hole (h+ )pairs,incomplete sunlight absorption,small specific surface area, and poor adsorption propertiesof g-C3N4 photocatalysts leaded to low photocatalytic eficiency,limiting their antibacterial efectiveess.Toovercome theseproblems,strategies suchas morphologycontrol,precious metaldeposition,elementdoping, and heterostructure construction were employed to functionalize g-C3N4 and fully activated its antibacterial potential. A detailed introduction was given to the optimization strategies for the photocatalytic antibacterial performance of g-C3N4 ,with a focus on thecurrent stateofresearchonitsphotocatalyticantibacterial propertiesin waterdisinfection,antibacterial dresings, antibacterial textiles,and food packaging.The challenges currently faced in the development of g-C3N4 photocatalytic antibacterialagentswerehighlighted.Inordertoaddresstheinreasinglyseverechalengeofmicrobialcontamination,future research directions are suggested:1) depening the research onthe mechanisms of reactive oxygen species(ROS) induced damage to bacterialcellmembranes,intracellular proteins,DNA,etal;2)exploring the antibacterialapplications of g-C3N4 on broad-spectrum bacteria such as drug-resistant bacteria and commonly used fungi; 3) enhancing the adaptability of g-C3N4 in different environments.

Keywords:catalytic chemistry;graphitic carbon nitride;photocatalysis;antibacterial;optimization strategy

受環(huán)境變化和人類活動(dòng)的影響,病原體的傳播風(fēng)險(xiǎn)增加,公眾在飲用水、使用公共設(shè)施以及處理傷口時(shí),很容易感染具有傳染性和致病性的微生物。(剩余23910字)

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